利用溶剂热法在铁基底上原位生长四方硫铁矿型FeS微米片阵列.通过改变实验参数,探索溶液中Fe3+浓度、硫源和溶剂对产物结构和形貌的影响.研究表明:Fe3+浓度与产物密集程度有关,浓度越高,片越密集;不同硫源释放S2-的速率不同,从而影响反应速率,S2-释放速率越快,片层形貌越不规则且产物中越容易产生杂质相;乙二胺作为溶剂,具有很强的协调能力和金属螯合力,对最终形成微米片阵列具有关键作用.
参考文献
| [1] | Zava(s)nik J;Stankovi (c) N et al.Sonochemical synthesis of mackinawite and the role of Cu addition on phase transformations in the Fe-S system[J].Journal of Nanoparticle Research,2014,16(2):1-13. |
| [2] | Sines IT;Vaughn DD et al.Synthesis of tetragonal mackinawite-type FeS nanosheets by solvothermal crystallization[J].Journal of Solid State Chemistry,2012,196:17-20. |
| [3] | 付铁岩,孙晋良,陈来,任慕苏.纳米催化剂FeS的制备及其在气相生长碳纤维中的应用[J].材料科学与工程学报,2005(05):549-551. |
| [4] | 袁斌霞,栾伟玲.溶剂热法快速合成纯相FeS2黄铁矿光电材料[J].材料科学与工程学报,2015(04):503-507,575. |
| [5] | Jae-Won Choi,Jae-Kwang Kim,Gouri Cheruvally,Jou-Hyeon Ahn,Ki-Won Kim,Hyo-Jun Ahn,Dong-Kyu Park.Improved Cycle Properties of FeS2 Cathode Material with Metallic Additives[J].材料科学与工程学报,2007(06):910-913. |
| [6] | 梁娜,陈敬超.FeS材料的制备、性能与应用[J].润滑与密封,2006(10):178-180,203. |
| [7] | Liu YD;Wang CB et al.The Effect of FeS solid lubricant on the tribological properties of bearing steel under grease lubrication[J].Tribology Transactions,2010,53(5):667-677. |
| [8] | Yang Y;Xie Y et al.Microscopic characteristic of biological iron sulfide composites during the generation process and the association with treatment effect on heavy metal wastewater[J].Water Science and Technology,2014,70(7):1292-1297. |
| [9] | Kim SH;Choi YJ;Kim DH;Jung SH;Kim KW;Ahn HJ;Ahn JH;Gu HB .The electrochemical properties of Li/FeS battery using electroless nickel plated FeS powder[J].Surface review and letters,2008(1-2):35-40. |
| [10] | Li L;Caban-Acevedo M et al.High-purity iron pyrite (FeS2) nanowires as high-capacity nanostructured cathodes for lithiumion batteries[J].Nanoscale,2014,6(4):2112-2118. |
| [11] | Liao F;Swiatowska J et al.The influence of the electrolyte on chemical and morphological modifications of an iron sulfide thin film negative electrode[J].Physical Chemistry Chemical Physics,2014,17(1):619-629. |
| [12] | Wang Y;Liao H et al.Effects of current collectors on electrochemical performance of FeS2 for li-ion battery[J].International Journal of Electrochemical Science,2013,8(3):4002-4009. |
| [13] | Yersak TA;Stoldt C et al.Electrochemical evolution of an iron sulfide and sulfur based cathode for all-solid-state li-ion batteries[J].Journal of the Electrochemical Society,2013,160(8):A1009-A1015. |
| [14] | Wang DW;Wang QH et al.Controlled growth of pyrite FeS2 crystallites by a facile surfactant-assisted solvothermal method[J].CRYSTENGCOMM,2010,12(3):755-761. |
| [15] | Qiu XQ;Liu M et al.Solution-based synthesis of pyrite films with enhanced photocurrent generation[J].Chemistry Communications,2013,49(12):1232-1234. |
| [16] | Paolella A;George C et al.Charge transport and electrochemical properties of colloidal greigite (Fe3S4) nanoplatelets[J].Chem Mat,2011,23(16):3762-3768. |
| [17] | Romano-Trujillo R;Rosendo E et al.Synthesis and characterization of PbSe nanoparticles obtained by a colloidal route using extran as a surfactant at low temperature[J].NANOTECHNOLOGY,2012,23(18):185602. |
| [18] | Yu SH;Yoshimura M .Fabrication of powders and thin films of various nickel sulfides by soft solution-processing routes[J].Advanced Functional Materials,2002,12(4):277-285. |
| [19] | Davey RJ;Black SN et al.Molecular design based on recognition at inorganic surfaces[J].NATURE,1991,353(6344):549-550. |
| [20] | Chen-Ho Lai;Kuo-Wei Huang;Ju-Hsiang Cheng .Direct growth of high-rate capability and high capacity copper sulfide nanowire array cathodes for lithium-ion batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(32):6638-6645. |
| [21] | Lu F;Cai WP;Zhang YG;Li Y;Sun FQ;Heo SH;Cho SO .Fabrication and field-emission performance of zinc sulfide nanobelt arrays[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(36):13385-13392. |
| [22] | Chen-Ho Lai;Kuo-Wei Huang;Ju-Hsiang Cheng .Oriented growth of large-scale nickel sulfide nanowire arrays via a general solution route for lithium-ion battery cathode applications[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2009(39):7277-7283. |
| [23] | Grijalva H;Inoue M et al.Amorphous and crystalline copper sulfides,CuS[J].Journal of Materials Chemistry,1996,6(7):1157-1160. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%